1. 个人简介：
2012年6月于安徽师范大学硕士研究生毕业后留校工作，2016年6月取得化学博士学位，2018年8月至2020年7月在香港理工大学应用生物与化学科技系做博士后研究。2022年12月，受聘副教授。目前主要从事新型有机功能染料的设计开发、性质及其在能源、材料、生物等领域的应用探索研究。至今以第一作者或通讯作者身份在Angew. Chem. Int. Ed.、Org. Lett.、Mater. Chem. Front.、J. Mater. Chem. C、Chem. Commun.等期刊上发表论文32篇。论文总被引2500余次。
学术研究方向：
1) 多硼氮芳香稠环的合成、性质及应用
2) 异吲哚吡咯染料的合成、性质及应用
科研工作经历：
2012.7 至 今，安徽师范大学，江南体育官网，硕士生导师
2018.8-2020.7，香港理工大学，应用生物与化学科技系，Postdoctoral Fellow，合作导师：Prof. Wong, Wai-Yeung
学习教育经历：
2013.9–2016.7，安徽师范大学，化学学科专业，博士，导师：焦莉娟 教授
2009.9–2012.6，安徽师范大学，有机化学专业，硕士，导师：焦莉娟 教授
2005.9–2009.7，安徽师范大学，应用化学专业，学士
2. 主持科研项目：
1) 2023年度安徽省高校科研项目，2023AH050149，高稳定高亮近红外二区双并氟硼二叱咯的设计开发与性质研究，2023.9-2026.8，在研
2）安徽省博士后研究人员科研活动项目，2021B533，高性能双硼肼桥联水杨酰腙吡咯荧光团的合成、性质及应用研究，2021.11-2023.11，在研
3) 安徽省自然科学青年基金项目，2008085QB67，新型立体扭曲双硼肼桥联水杨酰腙吡咯荧光团的设计合成、光学性质及自组装研究，2020.7-2022.6，已结题
4) 南京大学配位化学国家重点实验室开放基金，SKLCC1911，近红外二区AIE 型苯并四吡咯配合物的合成、性质及成像研究，2019.2-2021.1，已结题
5) 安徽师范大学博士启动基金，2017XJJ28，肼桥联吡咯类氟硼荧光染料的合成及性能研究，2017.5–2020.5，已结题
6) 国家自然科学基金青年基金项目，21402001，新型α,β位稠环Aza-BODIPY近红外染料的合成及性能研究，2015.1–2017.12，已结题
3. 实验室人员:
在读硕士生：
在读本科生：2023年创新实验-汪城、林昕、李涵琼、杨梦雪； 毕业设计-石深、石剑、项定睿、高育恒等
已毕业研究生：方兴宝（上海药明康德）、程超（南京药石科技）
1) Sun, Y.; Yu, C.;* Qian, W.; Zhang, H.; Jiao, L.; Li, J.;* Liu, M.;* Hao, E.* Dynamically stable co-assembled supramolecular BOPPY systems with chiral amplification. Chem. Commun. 2023, 59, 13986. DOI: 10.1039/d3cc04727j.
2) Wang, X.; Fu, X.; Bu, W.; Yu, C.;* Hao, E.; Jiao, L.; Wu,* Q.; Wang, R.; Wang, J.; Li, J.* Bisbenzothieno[b]-fused BODIPYs as efficient near-infrared heavy-atom-free photosensitizers. Dyes Pigments 2023, 11591. DOI: 10.1016/j.dyepig.2023.111591.
3) Yu, C.;* Sun, Y.; Wu, Q.; Shi, Y.; Jiao, L.; Guo, X.; Li J.;* Li, J.;* Hao, E.* Synthesis, properties, and semiconducting characteristics of bisbenzothieno[b]-fused BODIPYs. J. Org. Chem. 2023, DOI: 1.01021/acs.joc.3c01186.
4) Zhao, X.; Hu, B.; Zhou, Q.; Yu, Y.; Hao, E.; Guo, X,; Xu, Y.;* Yu, C.;* Sun, K.;* Lalevée, J.* Triphenylamine-substituted BODIPY dye based photoinitiators for free radical and cationic photopolymerization under visible LED irradiation and application in 3D printing. Dyes Pigments 2023, 111880. DOI: 10.1016/j.dyepig.2023.111880.
5) Yu, C.;* Sun, Y.; Jiao, L.; Hao, E.* Recent advances of highly fluorescent hydrazine inserted pyrrole-based bisboron-anchoring fluorophores: Synthesis and properties. Syn. Lett. 2023, DOI: 10.1055/a-2045-2369.
6) Yu, C.;* Sun, Y.; Fang, X.; Li, J.;* Wu, Q.; Bu, W.; Guo, X.; Wang, H.; Jiao, L.; Hao, E.* Aromatic-ring-fused BOPPY fluorophores: Synthesis, spectral, redox properties, and bioimaging application. Inorg. Chem. 2022, 61, 16718. DOI: 10.1021/acs.inorgchem.2c02517.
7) Yu, C.;* Fang, X.; Wu, Q.; Chen, N.; Cheng, C.; Guo, X.; Hao, E.*; Jiao, L.* Synthesis and spectral properties of aggregation-induced emission-active push-pull chromophores based on isoindole scaffolds. Org. Lett. 2022, 24, 4557. DOI: 10.1021/acs.orglett.2c01659.
8) 于长江;* 程超; 郝二红; 焦莉娟.* 芳并氮杂氟硼二吡咯的合成与应用. 《中国科学：化学》, 2022, 52, 1371. DOI: 10.1360/SSC-2022-0045.
9) Yu, C.;* Guo, X,; Fang, X.; Chen, Na; Wu, Q.; Hao, E.; Jiao, L.* Efficiently emissive, strongly slvatochromic and lipid droplet-specific, fluorescent probes for mapping polarity in vitro. Dyes Pigments 2022, 197, 109838. DOI: 10.1016/j.dyepig.2021.109838.
10) Yu, C.;* Fang, X.; Wang, H.; Guo, X,; Sun, L.; Wu, Q.; Jiao, L.; Hao, E.* A family of highly fluorescent and membrane-permeable bis(BF2) acyl-pyridinylhydrazine dyes with strong solid-state emission and large Stokes shifts: The BOAPH fluorophores. J. Org. Chem. 2021, 86, 11492. https://pubs.acs.org/doi/full/10.1021/acs.joc.1c01042
11) Guo, X.; Tang, B.; Wu, H.; Wu, Q.; Xie, Z.; Yu, C.;* Hao, E.; Jiao, L.* Bright near-infrared a-tetraphenyletheneBODIPY nanoprobes with high aggregated state emission quantum yields in aqueous system for lipid droplet-specific imaging. Mater. Chem. Front. 2021, 5, 3664. https://pubs.rsc.org/en/content/articlelanding/2021/qm/d1qm00067e/unauth
12) Zhao, Y.; Zhao, Y.; Yu, C.;* Liu, S.; Liu, Y.; Hao, E.;* Jiao, L.; Xu, X.; Zhang, Z.;* Li, J.* A novel family of non-symmetric benzothieno[7,6-b]-fused BODIPYs: Synthesis, structures, photophysical properties and lipid droplet-specific imaging in vitro. Dyes Pigments 2021, 196, 109748. https://www.sciencedirect.com/science/article/pii/S0143720821006148
13) Yu, C.; Fang, X.; Wu, Q.; Jiao, L.*; Sun, L.; Li, Z.; So, P.-K.; Wong, W.-Y.*; Hao, E.* A family of BODIPY-like, highly fluorescent and unsymmetrical Bis(BF2) pyrrolyl-acylhydrazone chromophore: BOAPY, Org. Lett. 2020, 22, 4588. DOI: 10.1021/acs.orglett.0c00940
14) Wu, H.; Guo, X.; Yu, C.;* Wong, W.-Y.; Hao, E.; Jiao, L.* Highly photostable ketopyrrolyl-BODIPYs with red aggregation-induced emission characteristics for ultrafast wash-free mitochondria-targeted bioimaging. Dyes Pigments 2020, 176, 108209. https://www.sciencedirect.com/science/article/pii/S0143720819329304
15) Yu, Y.; Yu, C.;* Wu, Q.; Wang, H.; Jiao, L.; Wong, W.-Y.; Hao, E.* Pure E/Z isomers of N-methylpyrrole-benzohydrazide-based BF2 complexes: Remarkable Aggregation-, crystallization-induced emission switching properties and application in sensing intracellular pH microenvironment. J. Mater. Chem. C 2019, 7, 4533. https://pubs.rsc.org/en/content/articlehtml/2019/tc/c9tc00473d
16) Yu, C.; Hao, E.;* Fang, X.; Wu, Q.; Wang, L.; Li, J.; Xu, L.; Jiao, L.;* Wong, W.-Y.* AIE-active difluoroboronated acyl hydrazone dyes (BOAHY) emitting across the entire visible region and their photo-switching properties. J. Mater. Chem. C 2019, 7, 3269. https://pubs.rsc.org/en/content/articlehtml/2019/tc/c9tc00316a
17) Yu, C.;+ Huang, Z.;+ Gu, W.; Wu, Q.; Hao, E.;* Xiao, Y.;* Jiao, L.;* Wong, W.-Y.* A novel family of AIE-active Meso-2-ketopyrrolylBODIPYs: Bright solid-state red fluorescence, morphological properties, and application as viscosimeters in live cells. Mater. Chem. Front. 2019, 3, 1823. https://pubs.rsc.org/en/content/articlehtml/2019/qm/c9qm00154a
18) Yu, Y.; Yu, C.;* Wu, Q.; Wang, H.; Jiao, L.; Wong, W.-Y.; Hao, E.* Pure E/Z isomers of N-methylpyrrole-benzohydrazide-based BF2 complexes: Remarkable Aggregation-, crystallization-induced emission switching properties and application in sensing intracellular pH microenvironment. J. Mater. Chem. C 2019, 7, 4533. https://pubs.rsc.org/en/content/articlehtml/2019/tc/c9tc00473d
19) Yu, C.; Huang, Z.; Wang, X.; Miao, W.; Wu, Q.; Wong, W.-Y.; Hao, E.;* Xiao, Y.;* Jiao L.* A family of highly fluorescent and unsymmetric Bis(BF2) chromophore containing both pyrrole and N-heteroarene derivatives: BOPPY. Org. Lett. 2018, 20, 4462. DOI: 10.1021/acs.orglett.8b01752
20) Yu, C.;* Li, T.; Wu, Q.; Hu, W.; Hao, E.; Jiao, L.* Synthesis structural and spectroscopic properties of quinoxaline-bridged bisBODIPYs. J. Porphyrins Phthalocyanines 2018, 22, 899. https://www.worldscientific.com/doi/abs/10.1142/S1088424618500797
21) Lv, X.; Li, T.; Wu, Q.; Yu, C.;* Jiao, L.; Hao, E.* Polybrominated BOPHY dyes: synthesis, reactivity, and properties. J. Org. Chem. 2018, 83, 1134. https://pubs.acs.org/doi/full/10.1021/acs.joc.7b02415
22) Yu, C.;* Miao, W.; Wang, J.; Hao, E.; Jiao, L.* PyrrolylBODIPYs: syntheses, properties, and application as environment-sensitive fluorescence probes. ACS Omega 2017, 2, 3551. https://pubs.acs.org/doi/full/10.1021/acsomega.7b00444
23) Cui, J.; Sheng, W.; Wu, Q.; Yu, C.;* Hao, E.; Bobadova-Parvanova, P.;* Storer, M.; Asiri, A. M.; Marwani, H. M.; Jiao, L.* Synthesis, structure, and properties of near-infrared [b]phenanthrene-fused BF2 azadipyrromethenes. Chem. Asian J. 2017, 12, 2486. (Very Important Paper) https://onlinelibrary.wiley.com/doi/abs/10.1002/asia.201700876
24) Yu, C.; Wu, Q.; Wang, J.; Wei, Y.; Hao, E.;* Jiao, L.* Red to near-infrared isoindole BODIPY fluorophores: synthesis, crystal structures, spectroscopic and electrochemical properties. J. Org. Chem. 2016, 81, 3761. https://pubs.acs.org/doi/full/10.1021/acs.joc.6b00414
25) Yu, C.; Wu, Q.; Wang, J.; Tian, Z.; Hao, E.;* Jiao, L.* Synthesis and photophysical properties of meso-aryloxy linked BODIPY monomers, dimers, and trimer. J. Porphyrins Phthalocyanines 2016, 20, 475. https://www.worldscientific.com/doi/abs/10.1142/S1088424616500309
26) Li, T.; Gu, W.; Yu, C.;* Lv, X.; Wang, H.; Hao, E.; Jiao, L.* Syntheses and photophysical properties of meso-phenylene bridged boron dipyrromethene monomers, dimers and trimer. Chin. J. Chem. 2016, 34, 989. https://onlinelibrary.wiley.com/doi/abs/10.1002/cjoc.201600500
27) Yu, C.; Jiao, L.;* Li, T.; Wu, Q.; Miao, W.; Wang, J.; Wei, Y.; Mu, X.; Hao, E.* Fusion and planarization of bisBODIPY: a new family of photostable near-infrared dyes. Chem. Commun. 2015, 51, 16852. https://pubs.rsc.org/en/content/articlehtml/2015/cc/c5cc07304a
28) Yu, C.; Hao, E.;* Li, T.; Wang, J.; Sheng, W.; Wei, Y.; Mu, X.; Jiao, L.* Dipyrrolylquinoxaline difluoroborates with intense red solid-state fluorescence. Dalton Trans. 2015, 44, 13897. (Hot Article) https://pubs.rsc.org/en/content/articlehtml/2015/dt/c5dt02012c
29) Yu, C.; Jiao, L.;* Zhang, P.; Feng, Z.; Cheng, C.; Wei, Y.; Mu, X. and Hao, E.* Highly fluorescent BF2 complexes of hydrazine-Schiff base linked bispyrrole, Org. Lett. 2014, 16, 3048. https://pubs.acs.org/doi/full/10.1021/ol501162f
30) Yu, C.; Jiao, L.; Hao, E. Research progress of functional modification of borondipyrromethene (BODIPY) fluorescent dyes. China Science paper 2013, 8, 1291. (in Chinese) http://www.paper.edu.cn/releasepaper/content/201301-1053/
31) Yu, C.; Jiao, L.;* Tan, X.; Wang, J.; Xu, Y.; Wu, Y.; Yang, G.; Wang, Z.; Hao, E.* Straightforward acid-catalyzed synthesis of pyrrolyldipyrromethenes. Angew. Chem. Int. Ed. 2012, 51, 7688. https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201202850
32) Yu, C.; Xu, Y.; Jiao, L.;* Zhou, J.; Wang, Z.; Hao, E.* Isoindole-BODIPY dyes as red to near-infrared fluorophores. Chem. Eur. J. 2012, 18, 6437. https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201200398
33) Yu, C.; Jiao, L.;* Yin, H.; Zhou, Z.; Pang, W.; Wu, Y.; Wang, Z.; Yang, G.; Hao, E. α-/β-formylated borondipyrrin (BODIPY) dyes: regioselective syntheses and photophysical properties. Eur. J. Org. Chem. 2011, 28, 5460. https://wiley.com/doi/full/10.1002/ejoc.201100736
34) Li, Z.; Zhang, L.; Wu, Q.; Li, H.; Kang, Z.; Yu, C.; Hao, E.*; Jiao, L.* Boron-Templated Synthesis of B(III)-Submonoazaporphyrins: The Hybrids of B(III)-Subporphyrins and B(III)-Subporphyrazines. J. Am. Chem. Soc. 2022, 144, 6692. https://pubs.acs.org/doi/full/10.1021/jacs.2c01671
35) Jiao, L.;* Yu, C.; Wang, J.; Briggs, E. A.; Besley, A. L.; Robinson, D.; Ruedas-Rama, M. J.; Orte, A.; Crovetto, L.; Talavera, E. M.; Alvarez-Pez, J. M.; Van der Auweraer, M.; Boens, N. Unusual Spectroscopic and Photophysical Properties of meso-tert-ButylBODIPY in Comparison to Related Alkylated BODIPY Dyes. RSC Adv. 2015, 5, 89375.
36) Jiao, L.;* Yu, C.; Liu, M.; Wu, Y.; Cong, K.; Meng, T.; Wang, Y.; Hao, E. Synthesis and functionalization of asymmetrical benzo-fused BODIPY dyes. J. Org. Chem. 2010, 75, 6035.
37) Jiao, L.;* Yu, C.; Uppal, T.; Liu, M.; Li, Y.; Zhou, Y.; Hao, E.; Hu, X.; Vicente, M. G. H.* Long-wavelength red fluorescent dyes from 3,5-diiodo-BODIPYs. Org. Biomol. Chem. 2010, 8, 2517.
38) Jiao, L.;* Yu, C.; Li, J.; Wang, Z.; Wu, M.; Hao, E. β-FormylBODIPYs from Vilsmeyer-Haack Reaction. J. Org. Chem. 2009, 74, 7525.
5. 授权专利:
1) 于长江，郝二宏，焦莉娟，黄维扬，异吲哚四吡咯色素及其制备方法, 中国发明专利，授权专利号：ZL 201911273748.8.
2) 于长江，张子瑜，焦莉娟，郝二红，苯并二吡咯酮氟硼荧光染料及其制备方法, 中国发明专利，授权专利号：ZL201911274610.X.
3) 于长江，郝二红，焦莉娟，黄维扬，酰基吡啶肼双氟硼强荧光染料及其制备方法, 中国发明专利，授权专利号：ZL201811258192.0.
4) 于长江，郝二红，焦莉娟，黄维扬，meso-吡咯酮BODIPY染料粘度探针及其制备方法和应用, 中国发明专利，授权专利号：ZL201811258191.6.
5) 于长江，郝二红，焦莉娟，黄维扬，吡咯吡啶肼双氟硼荧光染料及其制备方法和应用，中国发明专利，授权专利号：ZL201810499299.8.
6) 黄维扬，于长江，双异吲哚铱(III)配合物及其制备方法，中国发明专利，授权专利号：ZL202010160840.X.
7) 焦莉娟，于长江，吴昊，郝二红，氟硼荧光探针在线粒体定位中的应用，中国发明专利，授权专利号：ZL202010039832.X.
8) 郝二红，于长江，焦莉娟，黄维扬，线性共轭异吲哚多吡咯色素及其制备方法，中国发明专利，授权专利号：CN201911275827.2.
9) 郝二红，于长江，张年荣，焦莉娟，一类吡咯腙肼双氟硼荧光染料及其制备方法，中国发明专利，授权专利号：CN201810499260.6.
